Presenter Information

Katelyn Grenell, School of Pharmacy

Andrea Hough, Division of Medicinal Chemistry

Sahar Mofidi, Division of Medicinal Chemistry

Jane Cavanaugh, Division of Pharmacology

Kevin Tidgewell, Division of Medicinal Chemistry

Abstract

The role of natural products in drug development is well established. In recent years, marine cyanobacteria have been regarded as a major source of biologically active metabolites with chemical and Figure 5 pharmacological diversity. These cyanobacterial natural products serve as a promising source of drug A. leads for the discovery of therapeutic agents used in the treatment of many diseases of interest, such as CNS disorders, pain, and cancer. We have generated a library of 409 fractions from 37 field collected cyanobacterial samples and screened these fractions against a panel of CNS receptors using radiolabeled ligand competitive-binding assays. Upon analysis of the binding activity, we found that a significant amount of hits from our cyanobacterial samples were at the sigma 2 receptor. Sigma 2 has been known to be involved in CNS disorders and pain, as well as being upregulated in certain types of breast cancer, specifically, Triple Negative Breast Cancer (TNBC). For these reasons, certain cyanobacterial fractions with sigma 2 binding activity were prioritized and studied further using High-Performance Liquid Chromatography, Mass Spectrometry, and Nuclear Magnetic Resonance. Additionally, we found that fractions with a high affinity for sigma 2 had a significant cytotoxic effect on TNBC cell lines. The goal of this poster is to summarize our current analysis and results of cyanobacterial extracts with sigma 2 and TNBC cytotoxicity.

School

School of Pharmacy

Advisor

Kevin Tidgewell

Submission Type

Poster

Publication Date

April 2022

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Apr 20th, 12:00 AM

Discovery of Sigma-2 Ligands and Prioritization of Marine Cyanobacteria Extracts for TNBC Drug Discovery

The role of natural products in drug development is well established. In recent years, marine cyanobacteria have been regarded as a major source of biologically active metabolites with chemical and Figure 5 pharmacological diversity. These cyanobacterial natural products serve as a promising source of drug A. leads for the discovery of therapeutic agents used in the treatment of many diseases of interest, such as CNS disorders, pain, and cancer. We have generated a library of 409 fractions from 37 field collected cyanobacterial samples and screened these fractions against a panel of CNS receptors using radiolabeled ligand competitive-binding assays. Upon analysis of the binding activity, we found that a significant amount of hits from our cyanobacterial samples were at the sigma 2 receptor. Sigma 2 has been known to be involved in CNS disorders and pain, as well as being upregulated in certain types of breast cancer, specifically, Triple Negative Breast Cancer (TNBC). For these reasons, certain cyanobacterial fractions with sigma 2 binding activity were prioritized and studied further using High-Performance Liquid Chromatography, Mass Spectrometry, and Nuclear Magnetic Resonance. Additionally, we found that fractions with a high affinity for sigma 2 had a significant cytotoxic effect on TNBC cell lines. The goal of this poster is to summarize our current analysis and results of cyanobacterial extracts with sigma 2 and TNBC cytotoxicity.

 

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